1,5-bis-(N-benzyl-N,N-diethylammonium) diethylether, dichloride (BBDE Cl). A novel bis-ammonium salt as phase-transfer catalyst

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Title : 1,5-bis-(N-benzyl-N,N-diethylammonium) diethylether, dichloride (BBDE Cl). A novel bis-ammonium salt as phase-transfer catalyst
Author : Álvarez-Builla Gómez, Julio; Vaquero López, Juan José; García Navío, José Luis; Cabello, Juan F.; Sunkel Letelier, Carlos; Casa-Juana Muñoz, Miguel Fau de; Dorrego, Fernando; Santos Gil, Luis R.
Publisher : Pergamon Press
Date : 1990
Filiación : Universidad de Alcalá. Departamento de Química Orgánica
Patrocinadores : Authors wish to thank the Centro para el Desarrollo Tecnológico e Industrial from Spanish Ministerio de Industria y Energía, for financial support.
Cita bibliográfica : Tetrahedron, 1990, v. 46, n. 3, p. 967-978.
Keyword : 1,5-bis-(N-benzyl-N,N-diethylammonium) diethylether
Dichloride (BBDE Cl)
Bis-ammonium salt
Tipo de documento : info:eu-repo/semantics/article
Enlace permanente (URI) : http://hdl.handle.net/10017/3665
DOI : 10.1016/S0040-4020(01)81376-4
ISSN : 0040-4020
Versión : info:eu-repo/semantics/publishedVersion
Version of the editor : http://dx.doi.org/10.1016/S0040-4020(01)81376-4
Derechos : © Pergamon Press, 1990
Derechos de acceso : info:eu-repo/semantics/openAccess

Abstract :

1,5-Bis-(N-benzyl-N,N-diethylammionium)diethyl ether, dichloride (BBDE Cl) has been tested as phase transfer catalyst. Several test reactions have been performed, comparing yields obtained with several commercial catalysts, involving the transference of different nucleophiles. Williamson reactions on diphenols were used to test its ability in transferring dinucleophiles, producing higher yields at lower concentrations


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